I have a PS3 and a Vita, here is what I am anticipating in no particular order:
Deus Ex Human Revolution Director's Cut
Thief 4
Arkham Origins
Arkham Origins Blackgate
Proteus
Child of Light (Soooooo looking forward to this one!)
Whatever Giant Sparrow releases as their second Playstation exclusive (for their 3 game contract with Sony/Santa Monica)